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Season the chicken breasts with the kosher salt and ground black pepper. Heat the chicken stock in a medium saucepan and add the diced chicken breasts. Simmer until the chicken is no longer pink inside. Set aside.
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Seed and dice the red, yellow and green bell peppers. Mix together with the chopped red onion, frozen corn and minced garlic. Set aside.
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Mix together the black and white beans in a medium bowl, and then add the chopped tomatoes with chilies, the white wine vinegar, chili powder, cumin and cayenne. Mix the spices with the beans and tomatoes until well blended.
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Pour the cooked pieces of chicken with the broth into the bottom of a crockpot. Add the fresh vegetables, and then add the bean and tomato mixture.
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Cover the crockpot and turn the temperature to low. Cook for 4 to 5 hours.